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Many of the techniques often used to probe the microscopic properties of defects are ineffective for hydrogen containing complexes because passi-vated impurities are, in most cases, not electrically active or paramagnetic. InfraRed (IR) absorption and Raman spectroscopy, however, have been especially effective for characterizing hydrogen related defects [5.1,2]. The vibration of the light H in complexes occurs at frequencies well above intrinsic lattice absorption. In addition to the hydrogen vibrations, the perturbed local modes of the passivated dopant impurity can sometimes be studied. Once a vibrational fingerprint has been identified for a defect complex, it can be used to study the stability and chemical reactions of the complex. Vibrational spectroscopy is also well suited to the application of uniaxial stress techniques that provide information about defect symmetry and dynamics [5.3]. Further, the vibrational characteristics provide a benchmark for theoretical calculations of the configuration of complexes [5.4]. 2ff7e9595c
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